<?xml version="1.0" encoding="UTF-8" ?><?xml-stylesheet type="text/xsl" href="xsl/oaitohtml.xsl"?><OAI-PMH xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/ http://www.openarchives.org/OAI/2.0/OAI-PMH.xsd"><responseDate>2026-06-15T14:15:27Z</responseDate><request identifier="oai:doidb.wdc-terra.org:8268" metadataPrefix="oai_datacite" verb="GetRecord">http://doidb.wdc-terra.org/oaip/oai</request><GetRecord><record><header><identifier>oai:doidb.wdc-terra.org:8268</identifier><datestamp>2026-06-10T10:24:26Z</datestamp><setSpec>DOIDB</setSpec><setSpec>DOIDB.FID</setSpec></header><metadata><oai_datacite xmlns="http://schema.datacite.org/oai/oai-1.0/" xsi:schemaLocation="http://schema.datacite.org/oai/oai-1.0/ http://schema.datacite.org/oai/oai-1.0/oai.xsd"><isReferenceQuality>false</isReferenceQuality><schemaVersion>4</schemaVersion><datacentreSymbol>DOIDB.FID</datacentreSymbol><payload><resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance"
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   <identifier identifierType="DOI">10.5880/fidgeo.2025.006</identifier>
   <creators>
      <creator>
         <creatorName nameType="Personal">Franz, Gerhard</creatorName>
         <givenName>Gerhard</givenName>
         <familyName>Franz</familyName>
         <affiliation>Department of Applied Geosciences, Technical University Berlin, Berlin, Germany</affiliation>
      </creator>
      <creator>
         <creatorName nameType="Personal">Schiperski, Ferry</creatorName>
         <givenName>Ferry</givenName>
         <familyName>Schiperski</familyName>
         <affiliation>Department of Applied Geosciences, Technical University Berlin, Berlin, Germany</affiliation>
      </creator>
      <creator>
         <creatorName nameType="Personal">Khomenko, Vladimir</creatorName>
         <givenName>Vladimir</givenName>
         <familyName>Khomenko</familyName>
         <affiliation>The National Academy of Sciences, M. P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation, Kyiv, Ukraine</affiliation>
      </creator>
      <creator>
         <creatorName nameType="Personal">Gernert, Ulrich</creatorName>
         <givenName>Ulrich</givenName>
         <familyName>Gernert</familyName>
         <affiliation>Zentraleinrichtung Elektronenmikroskopie, Technical University Berlin, Berlin; Germany</affiliation>
      </creator>
      <creator>
         <creatorName nameType="Personal">Nissen, Jörg</creatorName>
         <givenName>Jörg</givenName>
         <familyName>Nissen</familyName>
         <affiliation>Zentraleinrichtung Elektronenmikroskopie, Technical University Berlin, Berlin; Germany</affiliation>
      </creator>
   </creators>
   <titles>
      <title>Colombian emeralds – internal and external growth and dissolution features</title>
   </titles>
   <publisher>GFZ Data Services</publisher>
   <publicationYear>2025</publicationYear>
   <subjects>
      <subject>EMPA</subject>
      <subject>micro-X-ray fluorescence</subject>
      <subject>SEM</subject>
      <subject>IR spectroscopy</subject>
      <subject>emeralds</subject>
      <subject subjectScheme="NASA/GCMD Earth Science Keywords">EARTH SCIENCE &gt; SOLID EARTH &gt; GEOCHEMISTRY</subject>
      <subject subjectScheme="NASA/GCMD Earth Science Keywords">EARTH SCIENCE &gt; SOLID EARTH &gt; ROCKS/MINERALS/CRYSTALS &gt; METAMORPHIC ROCKS</subject>
      <subject subjectScheme="NASA/GCMD Earth Science Keywords">EARTH SCIENCE &gt; SOLID EARTH &gt; ROCKS/MINERALS/CRYSTALS &gt; METAMORPHIC ROCKS &gt; METAMORPHIC ROCK PHYSICAL/OPTICAL PROPERTIES</subject>
   </subjects>
   <contributors>
      <contributor contributorType="ContactPerson">
         <contributorName>Franz, Gerhard</contributorName>
         <affiliation>Department of Applied Geosciences, Technical University Berlin, Berlin, Germany</affiliation>
      </contributor>
   </contributors>
   <resourceType resourceTypeGeneral="Dataset">Dataset</resourceType>
   <relatedIdentifiers>
      <relatedIdentifier relatedIdentifierType="DOI" relationType="IsSupplementTo">DOI of paper when available</relatedIdentifier>
      <relatedIdentifier relatedIdentifierType="DOI" relationType="Cites">10.1127/ejm/2018/0030-2703</relatedIdentifier>
      <relatedIdentifier relatedIdentifierType="DOI" relationType="Cites">10.5741/GEMS.51.3.222</relatedIdentifier>
      <relatedIdentifier relatedIdentifierType="DOI" relationType="Cites">10.15506/JoG.2021.38.1.26</relatedIdentifier>
      <relatedIdentifier relatedIdentifierType="DOI" relationType="Cites">10.5741/GEMS.59.1.46</relatedIdentifier>
   </relatedIdentifiers>
   <sizes/>
   <formats/>
   <rightsList>
      <rights rightsURI="http://creativecommons.org/licenses/by/4.0/">CC BY 4.0</rights>
   </rightsList>
   <descriptions>
      <description descriptionType="Abstract">Emeralds from Colombia are among the most highly-prized and valuable gemstones. Their growth phenomena including information about the geology of the area were described in detail by Pig-natelli et al. (2015, 2022) and Schmetzer and Martayan (2023). Here, we present data obtained by scanning electron microscopy (SEM), electron microprobe analysis (EMPA), and infrared absorption spectroscopy (IR) for five emerald crystals. The surface of the crystals shows both, growth phe-nomena as well as dissolution phenomena, the latter as etch pits (EP). Such EP have been used previously for other beryl types, mainly from pegmatitic environments (Kurumathoor and Franz, 2018); the Colombian emeralds come from low-grade metamorphosed black shales and thus offer the possibility to extend the use of EP as a provenance indicator to other types of beryl deposits. Internal structures are manifested in chemical zoning, investigated by EMPA and micro-X-ray fluo-rescence (µXRF). The crystals are characterized chemically by EMPA, polarized IR spectroscopy of oriented crystals showed the presence of fluids in the channels of the beryl structure.   <br/>
      </description>
   </descriptions>
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